五甲基环戊二烯基三(乙腈)六氟磷酸钌(II)
五甲基环戊二烯基三(乙腈)六氟磷酸钌(II)结构式
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常用名 | 五甲基环戊二烯基三(乙腈)六氟磷酸钌(II) | 英文名 | Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) |
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| CAS号 | 99604-67-8 | 分子量 | 504.41600 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C16H24F6N3PRu | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
J. Am. Chem. Soc. 123 , 12726, (2001)
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Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.
J. Am. Chem. Soc. 127 , 17644, (2005) The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is a... |
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