Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) structure
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Common Name | Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) | ||
|---|---|---|---|---|
| CAS Number | 99604-67-8 | Molecular Weight | 504.41600 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C16H24F6N3PRu | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Markovnikov alkyne hydrosilylation catalyzed by ruthenium complexes.
J. Am. Chem. Soc. 123 , 12726, (2001)
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Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: efficient and general trans addition.
J. Am. Chem. Soc. 127 , 17644, (2005) The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide range of alkynes. Terminal alkynes afford access to alpha-vinylsilane products with good regioselectivity. Deuterium labeling studies indicate a clean trans addition process is a... |
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