四氯环丙烯
四氯环丙烯结构式
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常用名 | 四氯环丙烯 | 英文名 | Tetrachlorocyclopropene |
|---|---|---|---|---|
| CAS号 | 6262-42-6 | 分子量 | 177.84400 | |
| 密度 | 1.45 g/mL at 25ºC(lit.) | 沸点 | 125-130ºC(lit.) | |
| 分子式 | C3Cl4 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 35.9ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Electrochemical preparation of tris(tert-butyldimethylsilyl)cyclopropene and its hydride abstraction to tris(tert-butyldimethylsilyl)cyclopropenium tetrafluoroborate.
Proc. Natl. Acad. Sci. U. S. A. 96(18) , 10003-5, (1999) Electrochemical reductive tert-butyldimethylsilylation of tetrachlorocyclopropene to 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene, a potential strained precursor for Diels-Alder and related cycloaddition reactions, is described. By hydride abstraction with... |
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3,3-Diethyl-and 3,3-dibenzyl-1,2-diferrocenylcyclopropenes.
Org. Biomol. Chem. 1(24) , 4458-64, (2003) Reactions of 2,3-diferrocenylcyclopropenone 1 with ethyl- and benzylmagnesium chlorides afford 3,3-diethyl-and 3,3-dibenzyl- 1,2-diferrocenylcyclopropenes 2 and 3, respectively, and products of nucleophilic opening of the three-membered ring resulting from th... |
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