Tetrachlorocyclopropene

Tetrachlorocyclopropene Structure
Tetrachlorocyclopropene structure
Common Name Tetrachlorocyclopropene
CAS Number 6262-42-6 Molecular Weight 177.84400
Density 1.45 g/mL at 25ºC(lit.) Boiling Point 125-130ºC(lit.)
Molecular Formula C3Cl4 Melting Point N/A
MSDS Chinese USA Flash Point 35.9ºC
Symbol GHS07
GHS07
Signal Word Warning

Electrochemical preparation of tris(tert-butyldimethylsilyl)cyclopropene and its hydride abstraction to tris(tert-butyldimethylsilyl)cyclopropenium tetrafluoroborate.

Proc. Natl. Acad. Sci. U. S. A. 96(18) , 10003-5, (1999)

Electrochemical reductive tert-butyldimethylsilylation of tetrachlorocyclopropene to 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene, a potential strained precursor for Diels-Alder and related cycloaddition reactions, is described. By hydride abstraction with...

3,3-Diethyl-and 3,3-dibenzyl-1,2-diferrocenylcyclopropenes.

Org. Biomol. Chem. 1(24) , 4458-64, (2003)

Reactions of 2,3-diferrocenylcyclopropenone 1 with ethyl- and benzylmagnesium chlorides afford 3,3-diethyl-and 3,3-dibenzyl- 1,2-diferrocenylcyclopropenes 2 and 3, respectively, and products of nucleophilic opening of the three-membered ring resulting from th...