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3-溴-2,2-二甲基-1-丙醇

3-溴-2,2-二甲基-1-丙醇结构式
3-溴-2,2-二甲基-1-丙醇结构式
品牌特惠专场
常用名 3-溴-2,2-二甲基-1-丙醇 英文名 3-Bromo-2,2-dimethyl-1-propanol
CAS号 40894-00-6 分子量 167.04400
密度 1.358 g/mL at 25 °C(lit.) 沸点 184-187 °C(lit.)
分子式 C5H11BrO 熔点 N/A
MSDS 中文版 美版 闪点 168 °F
符号 GHS07
GHS07
信号词 Warning

Novel diastereoselective synthesis of bicyclic beta-lactams through radical cyclization and their reduction toward 2-(1-alkoxy-2-hydroxyethyl)piperidines and 2-(1-alkoxy-2-hydroxyethyl)azepanes.

J. Org. Chem. 73(4) , 1422-8, (2008)

1-Allyl- and 1-(3-phenylallyl)-substituted 4-(2-bromo-1,1-dimethylethyl)azetidin-2-ones were transformed into 3-substituted 7-alkoxy-5,5-dimethyl-1-azabicyclo[4.2.0]octane-8-ones through radical cyclization by means of n-tributyltin hydride and AIBN in toluen...