3-Bromo-2,2-dimethyl-1-propanol

3-Bromo-2,2-dimethyl-1-propanol Structure
3-Bromo-2,2-dimethyl-1-propanol structure
Common Name 3-Bromo-2,2-dimethyl-1-propanol
CAS Number 40894-00-6 Molecular Weight 167.04400
Density 1.358 g/mL at 25 °C(lit.) Boiling Point 184-187 °C(lit.)
Molecular Formula C5H11BrO Melting Point N/A
MSDS Chinese USA Flash Point 168 °F
Symbol GHS07
GHS07
Signal Word Warning

Novel diastereoselective synthesis of bicyclic beta-lactams through radical cyclization and their reduction toward 2-(1-alkoxy-2-hydroxyethyl)piperidines and 2-(1-alkoxy-2-hydroxyethyl)azepanes.

J. Org. Chem. 73(4) , 1422-8, (2008)

1-Allyl- and 1-(3-phenylallyl)-substituted 4-(2-bromo-1,1-dimethylethyl)azetidin-2-ones were transformed into 3-substituted 7-alkoxy-5,5-dimethyl-1-azabicyclo[4.2.0]octane-8-ones through radical cyclization by means of n-tributyltin hydride and AIBN in toluen...