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2,2-五亚甲基-1,3-二氧六环基-4-酮

2,2-五亚甲基-1,3-二氧六环基-4-酮结构式
2,2-五亚甲基-1,3-二氧六环基-4-酮结构式
品牌特惠专场
常用名 2,2-五亚甲基-1,3-二氧六环基-4-酮 英文名 2,2-Pentamethylene-1,3-dioxolan-4-one
CAS号 4423-79-4 分子量 156.17900
密度 1.16g/cm3 沸点 70ºC0.5 mm Hg(lit.)
分子式 C8H12O3 熔点 32-35ºC(lit.)
MSDS 中文版 美版 闪点 221 °F
符号 GHS07
GHS07
信号词 Warning

An aldol-based approach to the asymmetric synthesis of L-callipeltose, the deoxyamino sugar of L-callipeltoside A.

Org. Lett. 3(20) , 3133-6, (2001)

[reaction: see text] The L-callipeltose subunit of L-callipeltoside A has been synthesized in 10 steps and 13% overall yield from D-threonine. The key steps are a highly diastereoselective Felkin anti aldol addition to a methyl ketone and a selective methylat...