2,2-Pentamethylene-1,3-dioxolan-4-one
2,2-Pentamethylene-1,3-dioxolan-4-one structure
|
Common Name | 2,2-Pentamethylene-1,3-dioxolan-4-one | ||
|---|---|---|---|---|
| CAS Number | 4423-79-4 | Molecular Weight | 156.17900 | |
| Density | 1.16g/cm3 | Boiling Point | 70ºC0.5 mm Hg(lit.) | |
| Molecular Formula | C8H12O3 | Melting Point | 32-35ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 221 °F | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
An aldol-based approach to the asymmetric synthesis of L-callipeltose, the deoxyamino sugar of L-callipeltoside A.
Org. Lett. 3(20) , 3133-6, (2001) [reaction: see text] The L-callipeltose subunit of L-callipeltoside A has been synthesized in 10 steps and 13% overall yield from D-threonine. The key steps are a highly diastereoselective Felkin anti aldol addition to a methyl ketone and a selective methylat... |
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