环丙甲醛
环丙甲醛结构式
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常用名 | 环丙甲醛 | 英文名 | Cyclopropanecarboxyldehyde |
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| CAS号 | 1489-69-6 | 分子量 | 70.090 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 99.5±0.0 °C at 760 mmHg | |
| 分子式 | C4H6O | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 7.2±0.0 °C | |
| 符号 |
GHS02, GHS05 |
信号词 | Danger |
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Synthesis and reactivity of six-membered oxa-nickelacycles: a ring-opening reaction of cyclopropyl ketones.
Chemistry 15(39) , 10083-91, (2009) Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta(2)-enonenickel complexes (2 a-c). In the presence of PCy(3... |
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Wang, Z. et al
Tetrahedron Lett. 41 , 4007, (2000)
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Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions.
J. Am. Chem. Soc. 128 , 13328, (2006) Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diastereoselective process. We report a palladium-catalyzed asym... |
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Structure-activity studies of 5-substituted pyridopyrimidines as adenosine kinase inhibitors.
Bioorg. Med. Chem. Lett. 11 , 83, (2001) The synthesis and SAR of a novel series of non-nucleoside pyridopyrimidine inhibitors of the enzyme adenosine kinase (AK) are described. It was found that pyridopyrimidines with a broad range of medium and large non-polar substituents at the 5-position potent... |