Cyclopropanecarboxyldehyde

Cyclopropanecarboxyldehyde Structure
Cyclopropanecarboxyldehyde structure
Common Name Cyclopropanecarboxyldehyde
CAS Number 1489-69-6 Molecular Weight 70.090
Density 1.2±0.1 g/cm3 Boiling Point 99.5±0.0 °C at 760 mmHg
Molecular Formula C4H6O Melting Point N/A
MSDS Chinese USA Flash Point 7.2±0.0 °C
Symbol GHS02 GHS05
GHS02, GHS05
Signal Word Danger

Synthesis and reactivity of six-membered oxa-nickelacycles: a ring-opening reaction of cyclopropyl ketones.

Chemistry 15(39) , 10083-91, (2009)

Cyclopropanecarboxaldehyde (1 a), cyclopropyl methyl ketone (1 b), and cyclopropyl phenyl ketone (1 c) were reacted with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) at 100 degrees C to give eta(2)-enonenickel complexes (2 a-c). In the presence of PCy(3...

Wang, Z. et al

Tetrahedron Lett. 41 , 4007, (2000)

Palladium-catalyzed asymmetric [3 + 2] trimethylenemethane cycloaddition reactions.

J. Am. Chem. Soc. 128 , 13328, (2006)

Transition-metal-catalyzed trimethylenemethane (TMM) [3 + 2] cycloadditions provide direct routes to functionalized cyclopentanes. This reaction has been shown to be a highly chemo-, regio-, and diastereoselective process. We report a palladium-catalyzed asym...

Structure-activity studies of 5-substituted pyridopyrimidines as adenosine kinase inhibitors.

Bioorg. Med. Chem. Lett. 11 , 83, (2001)

The synthesis and SAR of a novel series of non-nucleoside pyridopyrimidine inhibitors of the enzyme adenosine kinase (AK) are described. It was found that pyridopyrimidines with a broad range of medium and large non-polar substituents at the 5-position potent...