亚磷酸三乙酯
一般危化品
亚磷酸三乙酯结构式
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常用名 | 亚磷酸三乙酯 | 英文名 | Triethyl phosphite |
|---|---|---|---|---|
| CAS号 | 122-52-1 | 分子量 | 166.155 | |
| 密度 | 0.989 | 沸点 | 159.8±8.0 °C at 760 mmHg | |
| 分子式 | C6H15O3P | 熔点 | -112°C | |
| MSDS | 中文版 美版 | 闪点 | 54.1±18.7 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Warning |
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The sol-gel prepared SiO2-CaO-P2O5 composites doped with Metronidazole for application in local delivery systems.
Pharm. Dev. Technol. 17(6) , 697-704, (2012) The aim of this study was to evaluate the physical properties, chemical structure and bioactivity of sol-gel processed oxide (SiO(2)-CaO-P(2)O(5)) composites used as controlled release materials for Metronidazole-drug applied in periodontal disease treatment.... |
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Coordination chemistry of the solvated AgI and AuI ions in liquid and aqueous ammonia, trialkyl and triphenyl phosphite, and tri-n-butylphosphine solutions.
Inorg. Chem. 45(17) , 6912-21, (2006) The coordination chemistry of solvated Ag(I) and Au(I) ions has been studied in some of the most strong electron-pair donor solvents, liquid and aqueous ammonia, and the P donor solvents triethyl, tri-n-butyl, and triphenyl phosphite and tri-n-butylphosphine.... |
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Synthesis of 1,2-unsaturated pyranosylphosphonate nucleosides from 3,4,6-tri-O-acetyl-D-glycal.
Pharmazie 56(7) , 534-5, (2001) Ferrier rearrangement of 3,4,6-tri-O-acetyl-D-glucal (1) in the presence of triethylphosphite afforded the 2,3-unsaturated pyranose 2. Deacetylation and simultaneous migration of the double bond to 1,2-position in the sugar moiety was achieved by stirring in ... |
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Structure of solvated mercury(II) halides in liquid ammonia, triethyl phosphite and tri-n-butylphosphine solution.
Dalton Trans. (17) , 2303-13, (2008) Liquid ammonia, trialkyl phosphites, and especially trialkylphosphines, are very powerful electron-pair donor solvents with soft bonding character. The solvent molecules act as strongly coordinating ligands towards mercury(ii), interacting strongly enough to ... |
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Automated analysis of rabbit sperm motility and the effect of chemicals on sperm motion parameters.
Mol. Reprod. Dev. 33(3) , 347-56, (1992) Appropriate software settings and optimum procedures were determined for the measurement of the motion parameters of rabbit spermatozoa by the CellSoft (Cryo Resources Ltd., Montgomery, NY) computer-assisted digital image analysis system. The system was used ... |
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Pentanidium-catalyzed enantioselective α-hydroxylation of oxindoles using molecular oxygen.
Org. Lett. 14(18) , 4762-5, (2012) Pentanidium-catalyzed α-hydroxylation of 3-substituted-2-oxindoles using molecular oxygen has been developed with good yields and enantioselectivities. This reaction does not require an additional reductant such as triethyl phosphite, which was typically adde... |
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A Useful Synthesis of 1-Aminocyclopropanephosphonic Acid from Cyclopropanone Acetal.
J. Org. Chem. 64 , 4953, (1999)
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Copper-catalyzed tandem conjugate addition-electrophilic trapping: ketones, esters, and nitriles as terminal electrophiles.
J. Am. Chem. Soc. 126 , 4528, (2004) Exposure of enone substrates 1a-18a, which possess appendant ketone, ester, and nitrile moieties, to Et2Zn in the presence of catalytic Cu(OTf)2/P(OEt)3 provides the cyclized products in good to excellent yields and diastereoselectivities. These results repre... |
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Diazoalkane complexes of ruthenium with tris(pyrazolyl)borate and bis(pyrazolyl)acetate ligands.
Dalton Trans. 44 , 15470-80, (2015) Diazoalkane complexes [Ru(Tp)(N2CAr1Ar2)(PPh3)L]BPh4 ( and ) [Tp = tris(pyrazolyl)borate; L = P(OMe)3, P(OEt)3; Ar1 = Ar2 = Ph; Ar1 = Ph, Ar2 = p-tolyl; Ar1Ar2 = C12H8] were prepared by allowing chloro-compounds RuCl(Tp)(PPh3)L to react with diazoalkane in th... |
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Calcium phosphate sol-gel-derived thin films on porous-surfaced implants for enhanced osteoconductivity. Part I: Synthesis and characterization.
Biomaterials 25(22) , 5303-12, (2004) Thin sol-gel-formed calcium phosphate (Ca-P) films were formed on sintered porous-surfaced implants as an approach to increasing the rate of bone ingrowth. The films were prepared using either an inorganic precursor solution (with calcium nitrate tetrahydrate... |