邻硝基苯乙腈
邻硝基苯乙腈结构式
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常用名 | 邻硝基苯乙腈 | 英文名 | 2-Nitrophenylacetonitrile |
|---|---|---|---|---|
| CAS号 | 610-66-2 | 分子量 | 162.14500 | |
| 密度 | 1.272 g/cm3 | 沸点 | 178°C | |
| 分子式 | C8H6N2O2 | 熔点 | 82-85 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 138ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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Enantioselective total synthesis of (-)-strychnine using the catalytic asymmetric Michael reaction and tandem cyclization.
J. Am. Chem. Soc. 124(49) , 14546-7, (2002) The enantioselective total synthesis of (-)-strychnine was accomplished through the use of the highly practical catalytic asymmetric Michael reaction (0.1 mol % of (R)-ALB, more than kilogram scale, without chromatography, 91% yield and >99% ee) as well as a ... |
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Rapid access to α-carbolines via a one-pot tandem reaction of α,β-unsaturated ketones with 2-nitrophenylacetonitrile and the anti-proliferative activities of the products.
Org. Biomol. Chem. 12(2) , 355-61, (2014) An effective and convenient method has been developed for the preparation of 2 or 2,4-substituted α-carbolines via a one-pot tandem reaction of α,β-unsaturated ketones with 2-nitrophenylacetonitrile in the presence of zinc dust, acetic acid and triethylamine.... |
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