(S)-(+)-α-甲氧基-α-(三氟甲基)苯乙酰氯
(S)-(+)-α-甲氧基-α-(三氟甲基)苯乙酰氯结构式
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常用名 | (S)-(+)-α-甲氧基-α-(三氟甲基)苯乙酰氯 | 英文名 | (S)-(+)-alpha-methoxy-alpha-trifluoromethylphenylacetyl chloride |
|---|---|---|---|---|
| CAS号 | 20445-33-4 | 分子量 | 252.61800 | |
| 密度 | 1.35 g/mL at 25 °C(lit.) | 沸点 | 213-214 °C(lit.) | |
| 分子式 | C10H8ClF3O2 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 194 °F | |
| 符号 |
GHS05 |
信号词 | Danger |
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Six New Polyketide Decalin Compounds from Mangrove Endophytic Fungus Penicillium aurantiogriseum 328.
Mar. Drugs 13 , 6306-18, (2015) Six new compounds with polyketide decalin ring, peaurantiogriseols A-F (1-6), along with two known compounds, aspermytin A (7), 1-propanone,3-hydroxy-1- (1,2,4a,5,6,7,8,8a-octahydro-2,5-dihydroxy-1,2,6-trimethyl-1-naphthalenyl) (8), were isolated from the fer... |
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High-performance liquid chromatographic resolution of enantiomers of 1-phenyl-2-aminopropanes (amphetamines) with four chiral reagents.
J. Chromatogr. A. 307 , 335, (1984) High-performance liquid chromatography (HPLC) was employed for resolution of enantiomers of chiral ring-substituted 1-phenyl-2- aminopropanes (amphetamines) and 1-phenylethylamine following derivatization with four chiral reagents: (R)-(+)-1-phenylethyl isocy... |
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Mosher ester analysis for the determination of absolute configuration of stereogenic (chiral) carbinol carbons.
Nat. Protoc. 2 , 2451-2458, (2007) This protocol details the most commonly used nuclear magnetic resonance (NMR)-based method for deducing the configuration of otherwise unknown stereogenic, secondary carbinol (alcohol) centers (R1R2CHOH (or the analogous amines where OH is replaced by NH2)). ... |
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A novel asymmetric vinylogous tin-Pummerer rearrangement.
Org. Lett. 6 , 1757-1760, (2004) A new type of vinylogous tin-Pummerer rearrangement reaction was observed when benzyl tin derivatives containing a sulfinyl group at the ortho position were allowed to react with acyl chlorides or TFAA. The reaction is thought to proceed by nucleophilic attac... |
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Synthesis of beta-hydroxyaldehydes with stereogenic quaternary carbon centers by direct organocatalytic asymmetric aldol reactions.
Angew. Chem. Int. Ed. Engl. 43 , 2420-2423, (2004)
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Identification of two sex pheromone components of the potato aphid, Macrosiphum euphorbiae (Thomas).
J. Chem. Ecol. 30 , 819-834, (2004) Females of the potato aphid Macrosiphum euphorbiae exhibit typical calling behavior, with virgin female oviparae raising their back legs off the substrate to release sex pheromone from glands on the tibia. Airborne collections from calling oviparae were analy... |