三甲基乙醛
三甲基乙醛结构式
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常用名 | 三甲基乙醛 | 英文名 | Pivaldehyde |
|---|---|---|---|---|
| CAS号 | 630-19-3 | 分子量 | 86.132 | |
| 密度 | 0.8±0.1 g/cm3 | 沸点 | 77.5±0.0 °C at 760 mmHg | |
| 分子式 | C5H10O | 熔点 | 6 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | -13.2±7.8 °C | |
| 符号 |
GHS02, GHS07 |
信号词 | Danger |
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Tetrahedron Asymmetry 17 , 2659, (2006)
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Double stereodifferentiation in the catalytic asymmetric aziridination of imines prepared from α-chiral amines.
Chemistry 18(17) , 5302-13, (2012) The catalytic asymmetric aziridination of imines and diazo compounds (AZ reaction) mediated by boroxinate catalysts derived from the VANOL and VAPOL ligands was investigated with chiral imines derived from five different chiral, disubstituted, methyl amines. ... |
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Diastereomeric Reissert compounds of isoquinoline and 6,7-dimethoxy-3,4-dihydroisoquinoline in stereoselective synthesis.
J. Org. Chem. 72(15) , 5759-70, (2007) Chiral acid chlorides were reacted with isoquinoline and 6,7-dimethoxy-3,4-dihydroisoquinoline to form diastereomeric Reissert compounds 8-11 and 18-21, respectively. The best diastereoselectivity (80:20) was achieved in formation of the 9-phenylmenthyl deriv... |