1,1'-双(二叔丁基膦)二茂铁
1,1'-双(二叔丁基膦)二茂铁结构式
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常用名 | 1,1'-双(二叔丁基膦)二茂铁 | 英文名 | 1,1'-Bis(di-tert-butylphosphino)ferrocene |
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| CAS号 | 84680-95-5 | 分子量 | 474.420 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C26H44FeP2 | 熔点 | 73-75ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
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Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.
J. Org. Chem. 71 , 1969, (2006) The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur consecutively with heterocycle dehydrogenation in the prese... |
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A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine.
J. Am. Chem. Soc. 125 , 13326, (2003) A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three transformations (complexation, isomerization, and cyclizat... |
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Sergeyev, S.; Hesse, M.
Synlett 8 , 1313, (2002)
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Darbasie, N. D.; Schnatter, W. F. K. et al.
Tetrahedron Lett. 47 , 963, (2004)
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