1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene Structure
1,1'-Bis(di-tert-butylphosphino)ferrocene structure
Common Name 1,1'-Bis(di-tert-butylphosphino)ferrocene
CAS Number 84680-95-5 Molecular Weight 474.420
Density N/A Boiling Point N/A
Molecular Formula C26H44FeP2 Melting Point 73-75ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline.

J. Org. Chem. 71 , 1969, (2006)

The inter- and intramolecular couplings of unactivated alkenes to 3,4-dihydroquinazolines with a Rh(I) catalyst are reported. Coupling between olefins and NH-3,4-dihydroquinazoline was found to occur consecutively with heterocycle dehydrogenation in the prese...

A convenient one-pot procedure to afford bicyclic molecules by stereospecific iron carbonyl mediated [6 + 2] ene-type cyclization: a possible approach to gelsemine.

J. Am. Chem. Soc. 125 , 13326, (2003)

A convenient one-pot procedure to prepare angularly substituted bicyclic and tricyclic molecules with excellent diastereoselectivity in good yield was developed, by Fe(CO)5 promoted cyclization. Three transformations (complexation, isomerization, and cyclizat...

Sergeyev, S.; Hesse, M.

Synlett 8 , 1313, (2002)

Darbasie, N. D.; Schnatter, W. F. K. et al.

Tetrahedron Lett. 47 , 963, (2004)