亚乙基丙二酸二甲酯
亚乙基丙二酸二甲酯结构式
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常用名 | 亚乙基丙二酸二甲酯 | 英文名 | Dimethyl 2-ethylidenemalonate |
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| CAS号 | 17041-60-0 | 分子量 | 158.15200 | |
| 密度 | 1.111 g/mL at 25ºC(lit.) | 沸点 | 153.7ºC at 760 mmHg | |
| 分子式 | C7H10O4 | 熔点 | N/A | |
| MSDS | 中文版 美版 | 闪点 | 97ºC |
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Catalytic asymmetric Michael reactions with enamides as nucleophiles.
Angew. Chem. Int. Ed. Engl. 46(41) , 7803-5, (2007)
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Novel synthesis of conjugated dienes attached to a quaternary carbon center via Pd(0)-catalyzed deconjugative allylation of alkenylidenemalonates.
J. Org. Chem. 68(25) , 9858-60, (2003) Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various allylic acetates using LHMDS as a base in DMF in the presence ... |
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Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles Naota T, et al.
Chem. Commun. (Camb.) 1 , 63-64, (2001)
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