Dimethyl 2-ethylidenemalonate
Dimethyl 2-ethylidenemalonate structure
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Common Name | Dimethyl 2-ethylidenemalonate | ||
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| CAS Number | 17041-60-0 | Molecular Weight | 158.15200 | |
| Density | 1.111 g/mL at 25ºC(lit.) | Boiling Point | 153.7ºC at 760 mmHg | |
| Molecular Formula | C7H10O4 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 97ºC | |
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Catalytic asymmetric Michael reactions with enamides as nucleophiles.
Angew. Chem. Int. Ed. Engl. 46(41) , 7803-5, (2007)
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Novel synthesis of conjugated dienes attached to a quaternary carbon center via Pd(0)-catalyzed deconjugative allylation of alkenylidenemalonates.
J. Org. Chem. 68(25) , 9858-60, (2003) Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various allylic acetates using LHMDS as a base in DMF in the presence ... |
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Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles Naota T, et al.
Chem. Commun. (Camb.) 1 , 63-64, (2001)
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