Dimethyl 2-ethylidenemalonate
Modify Date: 2024-01-13 17:50:48
Dimethyl 2-ethylidenemalonate structure
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Common Name | Dimethyl 2-ethylidenemalonate | ||
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| CAS Number | 17041-60-0 | Molecular Weight | 158.15200 | |
| Density | 1.111 g/mL at 25ºC(lit.) | Boiling Point | 153.7ºC at 760 mmHg | |
| Molecular Formula | C7H10O4 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 97ºC | |
| Name | Dimethyl 2-ethylidenemalonate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.111 g/mL at 25ºC(lit.) |
|---|---|
| Boiling Point | 153.7ºC at 760 mmHg |
| Molecular Formula | C7H10O4 |
| Molecular Weight | 158.15200 |
| Flash Point | 97ºC |
| Exact Mass | 158.05800 |
| PSA | 52.60000 |
| LogP | 0.27870 |
| Vapour Pressure | 3.3mmHg at 25°C |
| Index of Refraction | n20/D 1.447(lit.) |
| Personal Protective Equipment | Eyeshields;Gloves |
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| Hazard Codes | Xn |
| RIDADR | NONH for all modes of transport |
| HS Code | 2917190090 |
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~97%
Dimethyl 2-ethy... CAS#:17041-60-0 |
| Literature: Sylla, Maite; Joseph, Delphine; Chevallier, Emilie; Camara, Cheikhou; Dumas, Francoise Synthesis, 2006 , # 6 p. 1045 - 1049 |
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~76%
Dimethyl 2-ethy... CAS#:17041-60-0 |
| Literature: Synthesis, , # 6 p. 1045 - 1049 |
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~%
Dimethyl 2-ethy... CAS#:17041-60-0 |
| Literature: Justus Liebigs Annalen der Chemie, , vol. 191, p. 69,72,74 |
| HS Code | 2917190090 |
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| Summary | 2917190090 acyclic polycarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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Catalytic asymmetric Michael reactions with enamides as nucleophiles.
Angew. Chem. Int. Ed. Engl. 46(41) , 7803-5, (2007)
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Novel synthesis of conjugated dienes attached to a quaternary carbon center via Pd(0)-catalyzed deconjugative allylation of alkenylidenemalonates.
J. Org. Chem. 68(25) , 9858-60, (2003) Palladium(0)-catalyzed deconjugative allylation of alkenylidenemalonates and alkylidenemalonates was achieved for the first time. Reactions of dimethyl 2-((E)-but-2-enylidene)malonate with various all... |
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Carbon-carbon bond forming reactions of N-bound transition metal a-cyanocarbanions: a mechanistic probe for catalytic Michael reactions of nitriles Naota T, et al.
Chem. Commun. (Camb.) 1 , 63-64, (2001)
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| MFCD00008447 |
| dimethyl 2-ethylidenepropanedioate |