氨基钠
氨基钠结构式
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常用名 | 氨基钠 | 英文名 | Sodamide |
|---|---|---|---|---|
| CAS号 | 7782-92-5 | 分子量 | 39.012 | |
| 密度 | 1.4 | 沸点 | 400 °C(lit.) | |
| 分子式 | H2NNa | 熔点 | 210 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 85 °F | |
| 符号 |
GHS02, GHS05, GHS09 |
信号词 | Danger |
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Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.
Dalton Trans. 43(46) , 17324-32, (2014) Trivalent Eu[N(SiHMe2)2]3(THF)2 can easily be synthesized by applying a routine salt metathesis protocol (EuCl3(THF)2 and 3 equiv. of Li[N(SiHMe2)2] in n-hexane) which crystallizes isotypically to its analogues of the rare-earth metal series (space group P21/... |
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Isotopic studies of the ammonia decomposition reaction mediated by sodium amide.
Phys. Chem. Chem. Phys. 17 , 22999-3006, (2015) We demonstrate that the ammonia decomposition reaction catalysed by sodium amide proceeds under a different mechanism to ammonia decomposition over transition metal catalysts. Isotopic variants of ammonia and sodium amide reveal a significant kinetic isotope ... |
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Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.
Org. Biomol. Chem. 9 , 2743-2750, (2011) Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise... |
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M. Bakavoli, et al.,
J. Heterocycl. Chem. 48 , 149-152, (2010)
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C. Caubere, et al.,
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K. G. Hampton, et al.,
Organic Synth. 51 , 128-132, (1971)
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