Sodamide

Sodamide Structure
Sodamide structure
Common Name Sodamide
CAS Number 7782-92-5 Molecular Weight 39.012
Density 1.4 Boiling Point 400 °C(lit.)
Molecular Formula H2NNa Melting Point 210 °C(lit.)
MSDS Chinese USA Flash Point 85 °F
Symbol GHS02 GHS05 GHS09
GHS02, GHS05, GHS09
Signal Word Danger

Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.

Dalton Trans. 43(46) , 17324-32, (2014)

Trivalent Eu[N(SiHMe2)2]3(THF)2 can easily be synthesized by applying a routine salt metathesis protocol (EuCl3(THF)2 and 3 equiv. of Li[N(SiHMe2)2] in n-hexane) which crystallizes isotypically to its analogues of the rare-earth metal series (space group P21/...

Isotopic studies of the ammonia decomposition reaction mediated by sodium amide.

Phys. Chem. Chem. Phys. 17 , 22999-3006, (2015)

We demonstrate that the ammonia decomposition reaction catalysed by sodium amide proceeds under a different mechanism to ammonia decomposition over transition metal catalysts. Isotopic variants of ammonia and sodium amide reveal a significant kinetic isotope ...

Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.

Org. Biomol. Chem. 9 , 2743-2750, (2011)

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise...

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J. Heterocycl. Chem. 48 , 149-152, (2010)

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