氰乙酸叔丁酯
氰乙酸叔丁酯结构式
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常用名 | 氰乙酸叔丁酯 | 英文名 | tert-Butyl 2-cyanoacetate |
|---|---|---|---|---|
| CAS号 | 1116-98-9 | 分子量 | 141.168 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 194.6±8.0 °C at 760 mmHg | |
| 分子式 | C7H11NO2 | 熔点 | 107-108ºC | |
| MSDS | 中文版 美版 | 闪点 | 79.0±5.2 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Modular isoquinoline synthesis using catalytic enolate arylation and in situ functionalization.
Org. Lett. 15(24) , 6190-3, (2013) A methyl ketone, an aryl bromide, an electrophile, and ammonium chloride were combined in a four-component, three-step, and one-pot coupling procedure to furnish substituted isoquinolines in overall yields of up to 80%. This protocol utilizes the palladium ca... |
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Synthesis of jenamidines A1/A2.
Org. Lett. 7(20) , 4519-22, (2005) [reaction: see text] Addition of the enolate of tert-butyl acetate to cyanamide methyl ester 17 followed by treatment with LHMDS afforded vinylogous urea 19 in 27% yield. Vinylogous urea 19 was also obtained from 37 and tert-butyl cyanoacetate in 50% yield. A... |
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