tert-Butyl 2-cyanoacetate
tert-Butyl 2-cyanoacetate structure
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Common Name | tert-Butyl 2-cyanoacetate | ||
|---|---|---|---|---|
| CAS Number | 1116-98-9 | Molecular Weight | 141.168 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 194.6±8.0 °C at 760 mmHg | |
| Molecular Formula | C7H11NO2 | Melting Point | 107-108ºC | |
| MSDS | Chinese USA | Flash Point | 79.0±5.2 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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Modular isoquinoline synthesis using catalytic enolate arylation and in situ functionalization.
Org. Lett. 15(24) , 6190-3, (2013) A methyl ketone, an aryl bromide, an electrophile, and ammonium chloride were combined in a four-component, three-step, and one-pot coupling procedure to furnish substituted isoquinolines in overall yields of up to 80%. This protocol utilizes the palladium ca... |
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Synthesis of jenamidines A1/A2.
Org. Lett. 7(20) , 4519-22, (2005) [reaction: see text] Addition of the enolate of tert-butyl acetate to cyanamide methyl ester 17 followed by treatment with LHMDS afforded vinylogous urea 19 in 27% yield. Vinylogous urea 19 was also obtained from 37 and tert-butyl cyanoacetate in 50% yield. A... |
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