偶氮二甲酸二异丙酯
偶氮二甲酸二异丙酯结构式
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常用名 | 偶氮二甲酸二异丙酯 | 英文名 | Diisopropyl azodicarboxylate |
|---|---|---|---|---|
| CAS号 | 2446-83-5 | 分子量 | 202.208 | |
| 密度 | 1.2±0.1 g/cm3 | 沸点 | 277.0±0.0 °C at 760 mmHg | |
| 分子式 | C8H14N2O4 | 熔点 | 3-5 °C | |
| MSDS | 中文版 美版 | 闪点 | 106.1±0.0 °C | |
| 符号 |
GHS07, GHS08, GHS09 |
信号词 | Warning |
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Diels-Alder hydrogels with enhanced stability: First step toward controlled release of bevacizumab.
Eur. J. Pharm. Biopharm. 96 , 217-25, (2015) Eight-armed PEG was functionalized with furyl and maleimide groups (8armPEG20k-Fur and 8armPEG20k-Mal); degradable hydrogels were obtained by cross-linking via Diels-Alder chemistry. To increase the stability to degradation, the macromonomers were modified by... |
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Molecularly imprinted polymers with synthetic dummy template for simultaneously selective removal and enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts.
J. Chromatogr. A. 1368 , 44-51, (2014) Dummy molecularly imprinted polymers (DMIPs) for simultaneously selective removal and enrichment of ginkgolic acids (GAs) during the processing of Ginkgo biloba leaves have been prepared. Two dummy template molecule with similar structural skeleton to GAs, 6-... |
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One-pot synthesis of an indole-substituted 7,8-dicarba-nido-dodecahydroundecaborate(-1).
Dalton Trans. 44(4) , 1748-53, (2014) Carbaboranes are increasingly used as pharmacophores to replace phenyl substituents in established drug molecules. In contrast to traditional organic chemistry, elaborate procedures to introduce functionality frequently fail in the case of carbaboranes and th... |
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[3,3]-rearrangements of phosphonium ylides.
J. Am. Chem. Soc. 128(14) , 4576-4577, (2006) Allylic phosphonium ylides are readily generated by the combination of an allylic alcohol, a carbene, and a chlorophosphite. Here we demonstrate that these intermediates undergo a thermal [3,3]-rearrangement to provide single isomers of homoallylic phosphonat... |