Diisopropyl azodicarboxylate

Diisopropyl azodicarboxylate Structure
Diisopropyl azodicarboxylate structure
Common Name Diisopropyl azodicarboxylate
CAS Number 2446-83-5 Molecular Weight 202.208
Density 1.2±0.1 g/cm3 Boiling Point 277.0±0.0 °C at 760 mmHg
Molecular Formula C8H14N2O4 Melting Point 3-5 °C
MSDS Chinese USA Flash Point 106.1±0.0 °C
Symbol GHS07 GHS08 GHS09
GHS07, GHS08, GHS09
Signal Word Warning

Diels-Alder hydrogels with enhanced stability: First step toward controlled release of bevacizumab.

Eur. J. Pharm. Biopharm. 96 , 217-25, (2015)

Eight-armed PEG was functionalized with furyl and maleimide groups (8armPEG20k-Fur and 8armPEG20k-Mal); degradable hydrogels were obtained by cross-linking via Diels-Alder chemistry. To increase the stability to degradation, the macromonomers were modified by...

Molecularly imprinted polymers with synthetic dummy template for simultaneously selective removal and enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts.

J. Chromatogr. A. 1368 , 44-51, (2014)

Dummy molecularly imprinted polymers (DMIPs) for simultaneously selective removal and enrichment of ginkgolic acids (GAs) during the processing of Ginkgo biloba leaves have been prepared. Two dummy template molecule with similar structural skeleton to GAs, 6-...

One-pot synthesis of an indole-substituted 7,8-dicarba-nido-dodecahydroundecaborate(-1).

Dalton Trans. 44(4) , 1748-53, (2014)

Carbaboranes are increasingly used as pharmacophores to replace phenyl substituents in established drug molecules. In contrast to traditional organic chemistry, elaborate procedures to introduce functionality frequently fail in the case of carbaboranes and th...

[3,3]-rearrangements of phosphonium ylides.

J. Am. Chem. Soc. 128(14) , 4576-4577, (2006)

Allylic phosphonium ylides are readily generated by the combination of an allylic alcohol, a carbene, and a chlorophosphite. Here we demonstrate that these intermediates undergo a thermal [3,3]-rearrangement to provide single isomers of homoallylic phosphonat...