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(R)-(+)-2-(氟二苯甲基)吡咯烷

(R)-(+)-2-(氟二苯甲基)吡咯烷结构式
(R)-(+)-2-(氟二苯甲基)吡咯烷结构式
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常用名 (R)-(+)-2-(氟二苯甲基)吡咯烷 英文名 (R)-(+)-2-(FLUORODIPHENYLMETHYL)PYRROLI&
CAS号 352535-00-3 分子量 255.33000
密度 1.098g/cm3 沸点 366.7ºC at 760mmHg
分子式 C17H18FN 熔点 N/A
MSDS 中文版 美版 闪点 175.6ºC
符号 GHS07
GHS07
信号词 Warning

Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.

Chemistry 36th ed., 18 , 11334-11342, (2012)

The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of intermediates that are central to organocatalytic processes. The...

Zimmer, L. E.; et al.

Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)

O'Hagan, D.; et al.

Tetrahedron Asymmetry 11 , 2033-2036, (2000)

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Angew. Chem. Int. Ed. Engl. 121 , 3111-3114, (2009)