(R)-(+)-2-(FLUORODIPHENYLMETHYL)PYRROLI& structure
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Common Name | (R)-(+)-2-(FLUORODIPHENYLMETHYL)PYRROLI& | ||
|---|---|---|---|---|
| CAS Number | 352535-00-3 | Molecular Weight | 255.33000 | |
| Density | 1.098g/cm3 | Boiling Point | 366.7ºC at 760mmHg | |
| Molecular Formula | C17H18FN | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 175.6ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | (2R)-2-[Fluoro(diphenyl)methyl]pyrrolidine |
|---|---|
| Synonym | More Synonyms |
| Density | 1.098g/cm3 |
|---|---|
| Boiling Point | 366.7ºC at 760mmHg |
| Molecular Formula | C17H18FN |
| Molecular Weight | 255.33000 |
| Flash Point | 175.6ºC |
| Exact Mass | 255.14200 |
| PSA | 12.03000 |
| LogP | 3.98050 |
| Index of Refraction | n20/D 1.577(lit.) |
| InChIKey | PGKMVPFJFKOUDA-MRXNPFEDSA-N |
| SMILES | FC(c1ccccc1)(c1ccccc1)C1CCCN1 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | 36/37/38 |
| Safety Phrases | 26-36 |
| RIDADR | NA 1993 / PGIII |
| HS Code | 2933990090 |
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(R)-(+)-2-(FLUO... CAS#:352535-00-3 |
| Literature: Sparr, Christof; Tanzer, Eva-Maria; Bachmann, Julia; Gilmour, Ryan Synthesis, 2010 , # 8 art. no. T20109SS, p. 1394 - 1397 |
| Precursor 1 | |
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| DownStream 0 | |
| HS Code | 2933990090 |
|---|---|
| Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
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Fluorinated organocatalysts for the enantioselective epoxidation of enals: molecular preorganisation by the fluorine-iminium ion gauche effect.
Chemistry 36th ed., 18 , 11334-11342, (2012) The fluorine-iminium ion gauche effect is triggered upon union of a secondary β-fluoroamine and an α,β-unsaturated aldehyde, providing a useful strategy for controlling the molecular topology of inter... |
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Zimmer, L. E.; et al.
Angew. Chem. Int. Ed. Engl. 123 , 12062-12074, (2011)
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O'Hagan, D.; et al.
Tetrahedron Asymmetry 11 , 2033-2036, (2000)
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| Pyrrolidine,2-(fluorodiphenylmethyl)-,(2R) |
| (R)-2-(fluorodiphenylmethyl)pyrrolidine |
| I11-1028 |