三丁基乙烯基锡
三丁基乙烯基锡结构式
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常用名 | 三丁基乙烯基锡 | 英文名 | (6-Butyl-5-decen-5-yl)-λ2-stannane |
|---|---|---|---|---|
| CAS号 | 7486-35-3 | 分子量 | 315.082 | |
| 密度 | 1.085 g/mL at 25 °C(lit.) | 沸点 | 104-106 °C3.5 mm Hg(lit.) | |
| 分子式 | C14H30Sn | 熔点 | <0ºC | |
| MSDS | 中文版 美版 | 闪点 | >230 °F | |
| 符号 |
GHS02, GHS06, GHS08, GHS09 |
信号词 | Danger |
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Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.
J. Am. Chem. Soc. 125 , 3718, (2003) This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a variety of functionalized, beta-hydrogen-containing alkyl bromid... |
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Palladium-catalyzed homogeneous coupling reactions of steroids with organostannanes.
Steroids 60(12) , 812-6, (1995) Direct and carbonylative coupling reactions of various steroid derivatives possessing iodo- and bromo-alkenyl moiety (17-iodo-androst-16-ene, 1, 17-bromoandrost-2,16-diene, 2, 17-iodo-4-aza-4-methylandrost-16-en-3-one, 3, 17-iodo-4-azaandrost-16-en-3-one, 4) ... |
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Palladium-catalyzed ring expansion reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. stereospecific synthesis of (Z)-2-(3-aryl-1-propenyl)cyclopentanones.
Org. Lett. 6 , 1979-1982, (2004) [reaction: see text] A novel type of cascade ring expansion process has been developed by the palladium-catalyzed reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. The reaction proceeds in a stereospecific manner to produce (Z)-2-(3-aryl-1-pr... |
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J. Org. Chem. 59 , 7164, (1994)
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Synthesis, biological activity, and three-dimensional quantitative structure-activity relationship model for a series of benzo[c]quinolizin-3-ones, nonsteroidal inhibitors of human steroid 5alpha-reductase 1.
J. Med. Chem. 47 , 3546-3560, (2004) New 5alpha-reductase 1 (5alphaR-1) inhibitors were designed to complete a consistent set of analogues suitable for a 3D QSAR study. These compounds were synthesized by a modification of the aza-Robinson annulation, further functionalized by Pd-catalyzed cross... |
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A.M. Echavarren, J.K. Stille
J. Am. Chem. Soc. 110 , 1557, (1988)
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W.J. Scott, J.E. McMurry
Acc. Chem. Res. 21 , 47, (1988)
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V. Farina et al.
J. Org. React. 50 , 1, (1998)
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