(6-Butyl-5-decen-5-yl)-λ2-stannane
(6-Butyl-5-decen-5-yl)-λ2-stannane structure
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Common Name | (6-Butyl-5-decen-5-yl)-λ2-stannane | ||
|---|---|---|---|---|
| CAS Number | 7486-35-3 | Molecular Weight | 315.082 | |
| Density | 1.085 g/mL at 25 °C(lit.) | Boiling Point | 104-106 °C3.5 mm Hg(lit.) | |
| Molecular Formula | C14H30Sn | Melting Point | <0ºC | |
| MSDS | Chinese USA | Flash Point | >230 °F | |
| Symbol |
GHS02, GHS06, GHS08, GHS09 |
Signal Word | Danger | |
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Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.
J. Am. Chem. Soc. 125 , 3718, (2003) This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a variety of functionalized, beta-hydrogen-containing alkyl bromid... |
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Palladium-catalyzed homogeneous coupling reactions of steroids with organostannanes.
Steroids 60(12) , 812-6, (1995) Direct and carbonylative coupling reactions of various steroid derivatives possessing iodo- and bromo-alkenyl moiety (17-iodo-androst-16-ene, 1, 17-bromoandrost-2,16-diene, 2, 17-iodo-4-aza-4-methylandrost-16-en-3-one, 3, 17-iodo-4-azaandrost-16-en-3-one, 4) ... |
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Palladium-catalyzed ring expansion reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. stereospecific synthesis of (Z)-2-(3-aryl-1-propenyl)cyclopentanones.
Org. Lett. 6 , 1979-1982, (2004) [reaction: see text] A novel type of cascade ring expansion process has been developed by the palladium-catalyzed reaction of (Z)-1-(1,3-butadienyl)cyclobutanols with aryl iodides. The reaction proceeds in a stereospecific manner to produce (Z)-2-(3-aryl-1-pr... |
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Synthesis, biological activity, and three-dimensional quantitative structure-activity relationship model for a series of benzo[c]quinolizin-3-ones, nonsteroidal inhibitors of human steroid 5alpha-reductase 1.
J. Med. Chem. 47 , 3546-3560, (2004) New 5alpha-reductase 1 (5alphaR-1) inhibitors were designed to complete a consistent set of analogues suitable for a 3D QSAR study. These compounds were synthesized by a modification of the aza-Robinson annulation, further functionalized by Pd-catalyzed cross... |
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