4,4',4''-三叔丁基2,2',6'2''-曲吡啶
4,4',4''-三叔丁基2,2',6'2''-曲吡啶结构式
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常用名 | 4,4',4''-三叔丁基2,2',6'2''-曲吡啶 | 英文名 | 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine |
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| CAS号 | 115091-29-7 | 分子量 | 401.58700 | |
| 密度 | 1.004g/cm3 | 沸点 | 535.7ºC at 760 mmHg | |
| 分子式 | C27H35N3 | 熔点 | 215-217ºC(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 220.4ºC | |
| 符号 |
GHS07 |
信号词 | Warning |
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A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species.
J. Am. Chem. Soc. 135(22) , 8141-4, (2013) Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this wor... |
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Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalyst.
J. Am. Chem. Soc. 128(40) , 13175-83, (2006) The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling reactions. Here, mechanistic studies using isotopically labeled ... |
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