4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine
4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine structure
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Common Name | 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine | ||
|---|---|---|---|---|
| CAS Number | 115091-29-7 | Molecular Weight | 401.58700 | |
| Density | 1.004g/cm3 | Boiling Point | 535.7ºC at 760 mmHg | |
| Molecular Formula | C27H35N3 | Melting Point | 215-217ºC(lit.) | |
| MSDS | Chinese USA | Flash Point | 220.4ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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A five-coordinate nickel(II) fluoroalkyl complex as a precursor to a spectroscopically detectable Ni(III) species.
J. Am. Chem. Soc. 135(22) , 8141-4, (2013) Mechanistic proposals for nickel-catalyzed coupling reactions often invoke five-coordinate alkyl- or aryl-bound Ni(II) and/or high-valent nickel(III) species, but because of their reactive nature, they have been difficult to study and fingerprint. In this wor... |
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Ligand redox effects in the synthesis, electronic structure, and reactivity of an alkyl-alkyl cross-coupling catalyst.
J. Am. Chem. Soc. 128(40) , 13175-83, (2006) The ability of the terpyridine ligand to stabilize alkyl complexes of nickel has been central in obtaining a fundamental understanding of the key processes involved in alkyl-alkyl cross-coupling reactions. Here, mechanistic studies using isotopically labeled ... |
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