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氯[三(2,4-二叔丁基苯基)亚磷酸]金

氯[三(2,4-二叔丁基苯基)亚磷酸]金结构式
氯[三(2,4-二叔丁基苯基)亚磷酸]金结构式
品牌特惠专场
常用名 氯[三(2,4-二叔丁基苯基)亚磷酸]金 英文名 CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD
CAS号 915299-24-0 分子量 879.34100
密度 N/A 沸点 N/A
分子式 C42H63AuClO3P 熔点 200-202ºC
MSDS 中文版 美版 闪点 N/A
符号 GHS07
GHS07
信号词 Warning

Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes.

J. Org. Chem. 19th ed., 73 , 7721, (2008)

Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cyclization is followed by most 1,6-eny...