氯[三(2,4-二叔丁基苯基)亚磷酸]金结构式
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常用名 | 氯[三(2,4-二叔丁基苯基)亚磷酸]金 | 英文名 | CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD |
|---|---|---|---|---|
| CAS号 | 915299-24-0 | 分子量 | 879.34100 | |
| 密度 | N/A | 沸点 | N/A | |
| 分子式 | C42H63AuClO3P | 熔点 | 200-202ºC | |
| MSDS | 中文版 美版 | 闪点 | N/A | |
| 符号 |
GHS07 |
信号词 | Warning |
|
Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes.
J. Org. Chem. 19th ed., 73 , 7721, (2008) Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cyclization is followed by most 1,6-eny... |
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