CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD

CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD Structure
CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD structure
Common Name CHLORO[TRIS(2,4-DI-TERT-BUTYLPHENYL)PHOSPHITE]GOLD
CAS Number 915299-24-0 Molecular Weight 879.34100
Density N/A Boiling Point N/A
Molecular Formula C42H63AuClO3P Melting Point 200-202ºC
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

Gold(I)-catalyzed intermolecular addition of carbon nucleophiles to 1,5- and 1,6-enynes.

J. Org. Chem. 19th ed., 73 , 7721, (2008)

Gold(I)-catalyzed addition of carbon nucleophiles to 1,6-enynes gives two different type of products by reaction at the cyclopropane or at the carbene carbons of the intermediate cyclopropyl gold carbenes. The 5-exo-dig cyclization is followed by most 1,6-eny...