双(1,5-环辛二烯)镍(0)
双(1,5-环辛二烯)镍(0)结构式
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常用名 | 双(1,5-环辛二烯)镍(0) | 英文名 | 1,2,5,6-cyclooctanetetraylidene, nickel salt |
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| CAS号 | 1295-35-8 | 分子量 | 266.992 | |
| 密度 | N/A | 沸点 | 153.5ºC at 760 mmHg | |
| 分子式 | C16H24Ni | 熔点 | 60 °C (dec.)(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 31.7ºC | |
| 符号 |
GHS02, GHS08 |
信号词 | Danger |
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Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.
Dalton Trans. 43(42) , 15997-6005, (2014) Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic sy... |
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Nickel-catalyzed thioallylation of alkynes with allyl phenyl sulfides.
Org. Lett. 9 , 263, (2007) Allylic sulfides add to alkynes in the presence of nickel complexes efficiently to afford thio-1,4-dienes regio- and stereoselectively. Functional groups such as alkoxy, siloxy, hydroxy, carboalkoxy, chloro, and cyano groups are tolerated. A mechanism that in... |
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A boron-doped helicene as a highly soluble, benchtop-stable green emitter.
Chem. Commun. (Camb.) 51(87) , 15808-10, (2015) The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility to the air- and water-stable green luminophore. |
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On the chiroptical behavior of conjugated multichromophoric compounds of a new pseudoaromatic class: bicolchicides and biisocolchicides.
PLoS ONE 5 , e10617, (2010) It is well known that, stemming from the mutual interplay between chromophores, circular dichroism (CD) is a powerful technique to deal with structural problems for both the small organic molecule and the biopolymer. However, quantitative interpretations of t... |
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J. Am. Chem. Soc. 111 , 6432, (1989)
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