二氯亚磷酸甲酯[亚磷酸化剂]
![二氯亚磷酸甲酯[亚磷酸化剂]结构式](https://image.chemsrc.com/caspic/278/3279-26-3.png)
二氯亚磷酸甲酯[亚磷酸化剂]结构式
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常用名 | 二氯亚磷酸甲酯[亚磷酸化剂] | 英文名 | Methyl dichlorophosphite |
|---|---|---|---|---|
| CAS号 | 3279-26-3 | 分子量 | 132.914 | |
| 密度 | 1.376 g/mL at 20 °C(lit.) | 沸点 | 89.4±9.0 °C at 760 mmHg | |
| 分子式 | CH3Cl2OP | 熔点 | −91 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 7.9±18.7 °C | |
| 符号 |
GHS02, GHS05, GHS07 |
信号词 | Danger |
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Radical deoxygenation of hydroxyl groups via phosphites.
J. Am. Chem. Soc. 126(41) , 13190-1, (2004) A highly efficient, two-step sequence method for the deoxygenation of hydroxyl groups has been developed. The method involves the preparation of the 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol using methyl dichlorophosphite and 2-(2-iodoph... |
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Facile synthesis of phosphonamidate- and phosphonate-linked phosphonopeptides.
J. Pept. Sci. 12(4) , 303-9, (2006) A direct method for the preparation of phosphonamidate- and phosphonate-linked phosphonopeptides has been developed. Using this method, both phosphonopeptides were prepared in acceptable yields directly from simple and commercially available chemicals in one-... |
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Syringe method for stepwise chemical synthesis of oligonucleotides.
Nucleic Acids Res. 10(10) , 3249-60, (1982) A simple procedure is described for synthesis of oligonucleotides by phosphate chemistry. Chains can be constructed rapidly with minimal equipment (a syringe and reagent bottles). The method is illustrated by synthesis of d-TGCAGGTT. Pertinent supporting data... |
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Synth. Commun. 22 , 289, (1992)
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J. Org. Chem. 58 , 5295, (1993)
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Synthesis of deoxyoligonucleotides on a polymer support. Matteucci MD and Caruthers MH.
J. Am. Chem. Soc. 103(11) , 3181-91, (1981)
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Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane. Gordon NJ and Evans Jr SA.
J. Org. Chem. 58(20) , 5295-97, (1993)
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