Methyl dichlorophosphite
Methyl dichlorophosphite structure
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Common Name | Methyl dichlorophosphite | ||
|---|---|---|---|---|
| CAS Number | 3279-26-3 | Molecular Weight | 132.914 | |
| Density | 1.376 g/mL at 20 °C(lit.) | Boiling Point | 89.4±9.0 °C at 760 mmHg | |
| Molecular Formula | CH3Cl2OP | Melting Point | −91 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 7.9±18.7 °C | |
| Symbol |
GHS02, GHS05, GHS07 |
Signal Word | Danger | |
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Radical deoxygenation of hydroxyl groups via phosphites.
J. Am. Chem. Soc. 126(41) , 13190-1, (2004) A highly efficient, two-step sequence method for the deoxygenation of hydroxyl groups has been developed. The method involves the preparation of the 2-(2-iodophenyl)ethyl methyl phosphite derivative of an alcohol using methyl dichlorophosphite and 2-(2-iodoph... |
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Facile synthesis of phosphonamidate- and phosphonate-linked phosphonopeptides.
J. Pept. Sci. 12(4) , 303-9, (2006) A direct method for the preparation of phosphonamidate- and phosphonate-linked phosphonopeptides has been developed. Using this method, both phosphonopeptides were prepared in acceptable yields directly from simple and commercially available chemicals in one-... |
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Syringe method for stepwise chemical synthesis of oligonucleotides.
Nucleic Acids Res. 10(10) , 3249-60, (1982) A simple procedure is described for synthesis of oligonucleotides by phosphate chemistry. Chains can be constructed rapidly with minimal equipment (a syringe and reagent bottles). The method is illustrated by synthesis of d-TGCAGGTT. Pertinent supporting data... |
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Synth. Commun. 22 , 289, (1992)
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J. Org. Chem. 58 , 5295, (1993)
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Synthesis of deoxyoligonucleotides on a polymer support. Matteucci MD and Caruthers MH.
J. Am. Chem. Soc. 103(11) , 3181-91, (1981)
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Synthesis and enantioselective aldol reaction of a chiral 2-oxo-2-propionyl-1, 3, 2-oxazaphosphorinane. Gordon NJ and Evans Jr SA.
J. Org. Chem. 58(20) , 5295-97, (1993)
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