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2-[(三丁基锡烷基)甲氧基]-乙胺

2-[(三丁基锡烷基)甲氧基]-乙胺结构式
2-[(三丁基锡烷基)甲氧基]-乙胺结构式
品牌特惠专场
常用名 2-[(三丁基锡烷基)甲氧基]-乙胺 英文名 SnAP M Reagent
CAS号 1557288-04-6 分子量 364.15
密度 N/A 沸点 367.9±48.0 °C(Predicted)
分子式 C15H35NOSn 熔点 N/A
MSDS 中文版 美版 闪点 N/A
符号 GHS06 GHS09
GHS06, GHS09
信号词 Danger

SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.

Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)

SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.

Nature Chemistry 6(4) , 310-4, (2014)

Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially medium-sized rings, are limited. We describe the developmen...

One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.

J. Am. Chem. Soc. 136(51) , 17726-9, (2014)

The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected spirocyclic amines are in great demand as scaffolds for dru...

SnAP reagents for the synthesis of piperazines and morpholines.

Org. Lett. 16(4) , 1236-9, (2014)

Substituted piperazines and morpholines are valuable structural motifs in biologically active compounds, but are not easily prepared by contemporary cross-coupling approaches. In this report, we introduce SnAP reagents for the transformation of aldehydes into...