4,7-二甲氧基-1,10-菲咯啉
4,7-二甲氧基-1,10-菲咯啉结构式
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常用名 | 4,7-二甲氧基-1,10-菲咯啉 | 英文名 | 4,7-Dimethoxy-1,10-phenanthroline |
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| CAS号 | 92149-07-0 | 分子量 | 240.257 | |
| 密度 | 1.3±0.1 g/cm3 | 沸点 | 373.1±37.0 °C at 760 mmHg | |
| 分子式 | C14H12N2O2 | 熔点 | 197-212ºC | |
| MSDS | 中文版 美版 | 闪点 | 135.9±16.8 °C | |
| 符号 |
GHS05, GHS07, GHS09 |
信号词 | Danger |
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4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles.
Org. Lett. 8 , 2779, (2006) [reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A variety of hindered and functionalized imidazoles and aryl... |
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Copper-catalyzed N-arylation of imidazoles and benzimidazoles.
J. Org. Chem. 72 , 6190, (2007) 4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides under mild conditions. Further optimization of the system has revealed that t... |
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A general and efficient copper catalyst for the amidation of aryl halides.
J. Am. Chem. Soc. 124 , 7421, (2002) An experimentally simple and inexpensive catalyst system was developed for the amidation of aryl halides by using 0.2-10 mol % of CuI, 5-20 mol % of a 1,2-diamine ligand, and K(3)PO(4), K(2)CO(3), or Cs(2)CO(3) as base. Catalyst systems based on N,N'-dimethyl... |
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Cu-catalyzed N- and O-arylation of 2-, 3-, and 4-hydroxypyridines and hydroxyquinolines.
Org. Lett. 9 , 643, (2007) With use of Cu-based catalysts, 2- and 4-hydroxypyridines were N-arylated in modest to excellent yields. In the case of 2-hydroxypyridine, the use of 4,7-dimethoxy-1,10-phenanthroline, 3, expanded the scope of previous literature reports to include the use of... |
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Li, C. S.; Dixon, D. D.
Tetrahedron Lett. 45 , 4257, (2004)
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