4,7-Dimethoxy-1,10-phenanthroline
4,7-Dimethoxy-1,10-phenanthroline structure
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Common Name | 4,7-Dimethoxy-1,10-phenanthroline | ||
|---|---|---|---|---|
| CAS Number | 92149-07-0 | Molecular Weight | 240.257 | |
| Density | 1.3±0.1 g/cm3 | Boiling Point | 373.1±37.0 °C at 760 mmHg | |
| Molecular Formula | C14H12N2O2 | Melting Point | 197-212ºC | |
| MSDS | Chinese USA | Flash Point | 135.9±16.8 °C | |
| Symbol |
GHS05, GHS07, GHS09 |
Signal Word | Danger | |
| Name | 4,7-Dimethoxy-1,10-phenanthroline |
|---|---|
| Synonym | More Synonyms |
| Density | 1.3±0.1 g/cm3 |
|---|---|
| Boiling Point | 373.1±37.0 °C at 760 mmHg |
| Melting Point | 197-212ºC |
| Molecular Formula | C14H12N2O2 |
| Molecular Weight | 240.257 |
| Flash Point | 135.9±16.8 °C |
| Exact Mass | 240.089874 |
| PSA | 44.24000 |
| LogP | 2.31 |
| Vapour Pressure | 0.0±0.8 mmHg at 25°C |
| Index of Refraction | 1.667 |
| InChIKey | ZPGVCQYKXIQWTP-UHFFFAOYSA-N |
| SMILES | COc1ccnc2c1ccc1c(OC)ccnc12 |
| Symbol |
GHS05, GHS07, GHS09 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H302-H318-H400 |
| Precautionary Statements | P273-P280-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xn: Harmful;N: Dangerous for the environment; |
| Risk Phrases | 22-41-50 |
| Safety Phrases | 26-39-61 |
| RIDADR | UN 3077 9/PG 3 |
| HS Code | 2933990090 |
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~72%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Liu, Xiang; Li, Xiaoyong; Chen, Yu; Hu, Yimin; Kishi, Yoshito Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6136 - 6139 |
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~%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Journal of Organic Chemistry, , vol. 72, # 16 p. 6190 - 6199 |
|
~77%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Levis, Michael; Luening, Ulrich; Mueller, Michael; Schmittel, Michael; Woehrle, Clemens Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1994 , vol. 49, # 5 p. 675 - 682 |
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~%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Journal of Organic Chemistry, , vol. 72, # 16 p. 6190 - 6199 |
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~%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Organic Letters, , vol. 8, # 13 p. 2779 - 2782 |
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~%
4,7-Dimethoxy-1... CAS#:92149-07-0 |
| Literature: Journal of Organic Chemistry, , vol. 27, p. 3878,3880 |
![5-[[2-[(2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ylidene)methylamino]anilino]methylidene]-2,2-dimethyl-1,3-dioxane-4,6-dione structure](https://image.chemsrc.com/caspic/471/503863-91-0.png)
CAS#:150-78-7| HS Code | 2933990090 |
|---|---|
| Summary | 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
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4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles.
Org. Lett. 8 , 2779, (2006) [reaction: see text] 4,7-Dimethoxy-1,10-phenanthroline (L) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazole with aryl iodides and bromides under mild conditions. A... |
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Copper-catalyzed N-arylation of imidazoles and benzimidazoles.
J. Org. Chem. 72 , 6190, (2007) 4,7-Dimethoxy-1,10-phenanthroline (L1c) was found to be an efficient ligand for the copper-catalyzed N-arylation of imidazoles and benzimidazoles with both aryl iodides and bromides under mild conditi... |
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A general and efficient copper catalyst for the amidation of aryl halides.
J. Am. Chem. Soc. 124 , 7421, (2002) An experimentally simple and inexpensive catalyst system was developed for the amidation of aryl halides by using 0.2-10 mol % of CuI, 5-20 mol % of a 1,2-diamine ligand, and K(3)PO(4), K(2)CO(3), or ... |
| 1,10-Phenanthroline, 4,7-dimethoxy- |
| 4,7-Dimethoxy-1,10-phenanthroline |
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- Product Name: 4,7-Dimethoxy-1,10-phenanthroline
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- China
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- Purity: 98.0%
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