亚磷酸三苯酯
一般危化品
亚磷酸三苯酯结构式
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常用名 | 亚磷酸三苯酯 | 英文名 | Triphenyl phosphite |
|---|---|---|---|---|
| CAS号 | 101-02-0 | 分子量 | 310.284 | |
| 密度 | 1.184 g/mL at 25 °C(lit.) | 沸点 | 360.0±11.0 °C at 760 mmHg | |
| 分子式 | C18H15O3P | 熔点 | 22-24 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 218.3±0.0 °C | |
| 符号 |
GHS07, GHS09 |
信号词 | Warning |
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Triphenyl phosphite, a new allergen in polyvinylchloride gloves.
Contact Dermatitis 68(1) , 42-9, (2013) Contact allergy to polyvinylchloride (PVC) gloves has been reported relatively seldom. In spring 2011, 5 of our patients had patch test reactions to PVC gloves. We obtained a collection of PVC raw materials from industrial producers and suppliers of chemical ... |
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Bioluminescent liquid light guide pad biosensor for indoor air toxicity monitoring.
Anal. Chem. 87(7) , 3655-61, (2015) Indoor air pollution became a recent concern found to be oftentimes worse than outdoor air quality. We developed a tool that is cheap and simple and enables continuous monitoring of air toxicity. It is a biosensor with both a nondisposable (monitor) and dispo... |
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Synthesis of tetra-substituted imidazoles and 2-imidazolines by Ni(0)-catalyzed dehydrogenation of benzylic-type imines.
Dalton Trans. 43(42) , 15997-6005, (2014) Ni(0)-catalyzed dehydrogenation of benzylic-type imines was performed to yield asymmetrical tetra-substituted imidazoles and 2-imidazolines. This was achieved with a single operational step while maintaining good selectivity and atom economy. The catalytic sy... |
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Helical polymers based on intramolecularly hydrogen-bonded aromatic polyamides.
Chem. Commun. (Camb.) 46(47) , 9019-21, (2010) Inspired by arylamide-based oligomeric foldermers that are stabilized by intramolecular hydrogen bonding, a series of polyamides with intramolecular hydrogen-bonding motifs were synthesized via polycondensation reactions. These polymers can fold into helical ... |
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Synthesis and characterization of novel, optically active polyamides derived from S-valine natural amino acid and bulky anthracenic side chain.
Amino Acids 39(5) , 1255-63, (2010) This is the first description of the application of molten tetrabutylammonium bromide (TBAB) in the presence of triphenyl phosphite (TPP) for the synthesis of novel polyamides (PAs). Monomer diacid, 5-[(9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboximido)-... |
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Effects of dark-rearing on triphenyl phosphate-induced neuropathy in the visual system of the developing European ferret (Mustela putorius furo).
J. Toxicol. Environ. Health A 58(4) , 215-31, (1999) Results of a previous study in our lab (Tanaka et al., 1994) suggested that the onset of susceptibility to the organophosphorus compound triphenyl phosphite (TPP) in the developing ferret visual system might be closely related to eye opening and the onset of ... |
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High-molecular weight serum cytotoxic factor in rats treated with triphenyl phosphite: an approach for biological monitoring.
J. Pharmacol. Toxicol. Methods 39(4) , 241-3, (1998)
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Cubane tetrameric complexes of copper(I) chloride and bromide with triphenyl phosphite.
Acta Crystallogr. C 55 ( Pt 2) , 162-5, (1999) The crystal structures of tetra-mu 3-chloro-tetrakis[(triphenyl phosphite-P)copper(I)], [Cu4Cl4(C18H15O3P)4], and tetra-mu 3-bromo-tetrakis [(triphenyl phosphite-P)-copper(I)], [Cu4Br4(C18H15O3P)4], are described. Both have distorted 'cubane' Cu4X4 cores. Dis... |
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A synthesis of phosphorylated dioxohexahydropyrimidines from N,N'-dimethylurea, activated acetylenes, and trialkyl phosphites.
Mol. Divers. 14(4) , 617-20, (2010) An efficient synthesis of alkyl 5-(dialkoxy- phosphoryl)-1,3-dimethyl-2, 6-dioxo-hexahydropyrimidine-4-carboxylates is described. This involves the reaction of N,N'-dimethylurea and dialkyl acetylendicarboxylates in the presence of trialkyl phosphites. Under ... |
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A quantitative assessment of TPP-induced delayed neuropathy in the retina and lateral geniculate nucleus of the European ferret (Mustela putorius furo).
Neurotoxicology 23(1) , 33-42, (2002) Triphenyl phosphite (TPP) has been examined extensively in our lab to assess its degenerative effects on the visual pathway of the European ferret. Tanaka et al. [Fundam. Appl. ToxicoL 22 (1994) 577; J. Toxicol. Environ. Health 58 (1999) 215] reported an age-... |