硼烷吡啶络合物
硼烷吡啶络合物结构式
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常用名 | 硼烷吡啶络合物 | 英文名 | Trihydrido(pyridine)boron |
|---|---|---|---|---|
| CAS号 | 110-51-0 | 分子量 | 92.935 | |
| 密度 | 0.929 g/mL at 20 °C | 沸点 | 102 °C (0.37505 mmHg) | |
| 分子式 | C5H8BN | 熔点 | 10-11 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 70 °F | |
| 符号 |
GHS02, GHS06 |
信号词 | Danger |
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Dendritic Glycopolymer as Drug Delivery System for Proteasome Inhibitor Bortezomib in a Calcium Phosphate Bone Cement: First Steps Toward a Local Therapy of Osteolytic Bone Lesions.
Macromol. Biosci. 15 , 1283-95, (2015) Establishment of drug delivery system (DDS) in bone substitute materials for local treatment of bone defects still requires ambitious solutions for a retarded drug release. We present two novel DDS, a weakly cationic dendritic glycopolymer and a cationic poly... |
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Hydroboration with pyridine borane at room temperature.
J. Am. Chem. Soc. 127 , 5766-5767, (2005) Treatment of pyridine borane (Py.BH3) with iodine, bromine, or strong acids affords activated Py.BH2X complexes that are capable of hydroborating alkenes at room temperature. Evidence is presented for an unusual hydroboration mechanism involving leaving group... |
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Global amine and acid functional group modification of proteins.
Anal. Chem. 80(3) , 713-20, (2008) A sequential reaction methodology is employed for the complete derivatization of protein thiols, amines, and acids in high purity under denaturing conditions. Following standard thiol alkylation, protein amines are modified via reductive methylation with form... |
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Pyridine borane as a reducing agent for proteins.
Anal. Biochem. 139(1) , 58-67, (1984) Pyridine borane has been reported as a superior reagent over a wide pH range, 5-9, for the reductive methylation of amino groups of proteins with formaldehyde [J. C. Cabacungan , A. I. Ahmed , and R. E. Feeney (1982) Anal. Biochem. 124, 272-278]. It has also ... |
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An application of borane as a protecting group for pyridine.
J. Org. Chem. 73(17) , 6899-901, (2008) Efforts to couple 4 with 12 employing base mediation are problematic due to the formation of 6. To circumvent this issue, 12 was converted to the pyridine borane complex (13). Alkylation of 4 with 13 provided 3 after removal of the borane under acidic conditi... |
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Fast mass spectrometry detection of tryptophan-containing peptides and proteins by reduction with pyridine-borane.
Anal. Biochem. 440(1) , 12-4, (2013) In this note, we describe a method devised to detect, by means of mass spectrometry (MS), tryptophan-containing peptides and proteins using pyridine-borane. This reagent selectively reduces tryptophan residues, converting them to 2,3-dihydro-tryptophan, there... |
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Aldrichimica Acta 6 , 51, (1973)
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Synth. Commun. 23 , 789, (1993)
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J. Chem. Soc. Perkin Trans. I , 717, (1984)
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