10-十一碳炔酸
10-十一碳炔酸结构式
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常用名 | 10-十一碳炔酸 | 英文名 | 10-Undecynoic acid |
|---|---|---|---|---|
| CAS号 | 2777-65-3 | 分子量 | 182.259 | |
| 密度 | 1.0±0.1 g/cm3 | 沸点 | 297.7±23.0 °C at 760 mmHg | |
| 分子式 | C11H18O2 | 熔点 | 40-42 °C(lit.) | |
| MSDS | 中文版 美版 | 闪点 | 142.9±17.3 °C | |
| 符号 |
GHS07 |
信号词 | Warning |
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Simultaneous electropolymerization and electro-click functionalization for highly versatile surface platforms.
ACS Nano 8(5) , 5240-8, (2014) Simple preparation methods of chemically versatile and highly functionalizable surfaces remain rare and present a challenging research objective. Here, we demonstrate a simultaneous electropolymerization and electro-click functionalization process (SEEC) for ... |
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Amphiphilic polyesters derived from silylated and germylated fatty compounds.
Biomacromolecules 10(4) , 850-7, (2009) New classes of amphiphilic polyesters were prepared from metallated (Si, Ge) fatty methyl ester (FAME) precursors and poly(tetramethylene oxide) glycol. Hydrosilylation of 10-undecenoic methyl ester by tetramethyldisiloxane occurred at 80 degrees C in the pre... |
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Cellulose/water: liquid/gas and liquid/liquid phase equilibria and their consistent modeling.
Biomacromolecules 8(6) , 1865-72, (2007) Liquid/liquid and liquid/gas equilibria were measured for the water/cellulose system at 80 degrees C using three different polymer samples. For these experiments we prepared cellulose films of approximately 20-25 microm in thickness and determined their equil... |
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Mechanism-based in vivo inactivation of lauric acid hydroxylases.
Biochemistry 25(16) , 4705-11, (1986) The hepatic cytochrome P-450 isozymes that catalyze omega- and (omega - 1)-hydroxylation of lauric acid are specifically inactivated in vitro but not in vivo by 10-undecynoic acid. The lack of in vivo activity may result from rapid degradation of the inhibito... |
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10-Undecynoic acid, an inhibitor of cytochrome P450 4A1, inhibits ethanolamine-specific phospholipid base exchange reaction in rat liver microsomes.
Acta Biochim. Pol. 46(1) , 203-10, (1999) 1,12-Dodecanedioic acid, the end-product of omega-hydroxylation of lauric acid, stimulates in a concentration dependent manner, phosphatidylethanolamine synthesis via ethanolamine-specific phospholipid base exchange reaction in rat liver endoplasmic reticulum... |
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Specific inactivation of hepatic fatty acid hydroxylases by acetylenic fatty acids.
J. Biol. Chem. 259(7) , 4136-41, (1984) The terminal acetylenic analogue of lauric acid, 11-dodecynoic acid (11-DDYA), specifically inactivates hepatic cytochrome P-450 enzymes that catalyze omega- and omega-1-hydroxylation of lauric acid. The inactivation, as required for a suicidal process, is NA... |
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Biocompatible functionalisation of starch.
Chem. Commun. (Camb.) 47(2) , 683-5, (2011) The enzyme catalysed esterification of starch and fatty acids with terminal triple bonds is described. This material can be used as an acceptor for azide containing molecules, through azide/alkyne cycloaddition. The potential is illustrated by the production ... |
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Determination of microsomal lauric acid hydroxylase activity by HPLC with flow-through radiochemical quantitation.
Anal. Biochem. 170(1) , 83-93, (1988) An assay for the microsomal hydroxylation of lauric acid (LA), based on HPLC with flow-through radiochemical detection, has been developed. Conditions were optimized for resolution and quantitation of three microsomal metabolites of LA, one of which has not b... |
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Microwave irradiated click reactions on silicon surfaces via derivertization of covalently grafted poly(PEGMA) brushes.
J. Colloid. Interface Sci. 358(1) , 116-22, (2011) Two surface chemistry approaches were realized to complete click reactions at covalently grafted polymer brushes of poly(poly(ethylene glycol) monomethacrylate) on a planar silicon surface (Si-g-P(PEGMAOH)). On one hand, the hydroxyls from Si-g-P(PEGMA-OH) br... |
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Polyurethane networks from fatty-acid-based aromatic triols: synthesis and characterization.
Biomacromolecules 8(6) , 1858-64, (2007) Novel biobased aromatic triols (1,3,5-(9-hydroxynonyl)benzene and 1,3,5-(8-hydroxyoctyl)-2,4,6-octylbenzene) were synthesized through the transition-metal-catalyzed cyclotrimerization of two alkyne fatty acid methyl esters (methyl 10-undecynoate and methyl 9-... |