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1-甲氧基-1,3-环己二烯

1-甲氧基-1,3-环己二烯结构式
1-甲氧基-1,3-环己二烯结构式
品牌特惠专场
常用名 1-甲氧基-1,3-环己二烯 英文名 1-methoxycyclohexa-1,3-diene
CAS号 2161-90-2 分子量 110.15400
密度 0.93g/cm3 沸点 143.8ºC at 760mmHg
分子式 C7H10O 熔点 N/A
MSDS 中文版 美版 闪点 51.1ºC
符号 GHS02 GHS07
GHS02, GHS07
信号词 Warning

Remote Regiocontrol by a Thioether Group in Diels-Alder Reactions of Naphthazarin: Regioselective Access to Tetracyclic Polyhydroxyquinones.

J. Org. Chem. 61(18) , 6136-6138, (1996)

The synthesis of tetracyclic polyhydroxyquinones 5a and 5b was achieved through a sequence involving two Diels-Alder reactions with 1-methoxy-1,3-cyclohexadiene: the first with 2-(p-tolylthio)naphthazarin and the second on the resulting tricyclic derivative p...

Synthesis of tetra-ortho-substituted, phosphorus-containing and carbonyl-containing biaryls utilizing a Diels-Alder approach.

J. Am. Chem. Soc. 129(29) , 9109-16, (2007)

The application of the Diels-Alder approach to biaryls (DAB) is described for the synthesis of tetra-ortho-substituted biaryl compounds containing orthogonally functionalized substituents. The syntheses of phosphorus-containing, disubstituted alkynes and carb...

Diels-Alder approach to biaryls (DAB): importance of the ortho-nitro moiety in the [4 + 2] cycloaddition.

Org. Biomol. Chem. 6(2) , 255-7, (2008)

A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition-cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target biaryls in superior yields as compared to the meta and para...

Stereoselective synthesis of dihydroisocoumarin moiety of microbial agent AI-77-B: a Diels-Alder based strategy. Ghosh AK and Cappiello J.

Tetrahedron Lett. 39(48) , 8803-6, (1998)