1-methoxycyclohexa-1,3-diene
1-methoxycyclohexa-1,3-diene structure
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Common Name | 1-methoxycyclohexa-1,3-diene | ||
|---|---|---|---|---|
| CAS Number | 2161-90-2 | Molecular Weight | 110.15400 | |
| Density | 0.93g/cm3 | Boiling Point | 143.8ºC at 760mmHg | |
| Molecular Formula | C7H10O | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 51.1ºC | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
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Remote Regiocontrol by a Thioether Group in Diels-Alder Reactions of Naphthazarin: Regioselective Access to Tetracyclic Polyhydroxyquinones.
J. Org. Chem. 61(18) , 6136-6138, (1996) The synthesis of tetracyclic polyhydroxyquinones 5a and 5b was achieved through a sequence involving two Diels-Alder reactions with 1-methoxy-1,3-cyclohexadiene: the first with 2-(p-tolylthio)naphthazarin and the second on the resulting tricyclic derivative p... |
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Synthesis of tetra-ortho-substituted, phosphorus-containing and carbonyl-containing biaryls utilizing a Diels-Alder approach.
J. Am. Chem. Soc. 129(29) , 9109-16, (2007) The application of the Diels-Alder approach to biaryls (DAB) is described for the synthesis of tetra-ortho-substituted biaryl compounds containing orthogonally functionalized substituents. The syntheses of phosphorus-containing, disubstituted alkynes and carb... |
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Diels-Alder approach to biaryls (DAB): importance of the ortho-nitro moiety in the [4 + 2] cycloaddition.
Org. Biomol. Chem. 6(2) , 255-7, (2008) A series of nitrophenyl acetylenes were evaluated for their utility in a cycloaddition-cycloreversion approach to polysubstituted biaryls. ortho-Nitrophenyl acetylene consistently provided the target biaryls in superior yields as compared to the meta and para... |
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Stereoselective synthesis of dihydroisocoumarin moiety of microbial agent AI-77-B: a Diels-Alder based strategy. Ghosh AK and Cappiello J.
Tetrahedron Lett. 39(48) , 8803-6, (1998)
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