Bis(trimethylsilyl) malonate

Modify Date: 2024-01-14 23:21:13

Bis(trimethylsilyl) malonate Structure
Bis(trimethylsilyl) malonate structure
Common Name Bis(trimethylsilyl) malonate
CAS Number 18457-04-0 Molecular Weight 248.424
Density 1.0±0.1 g/cm3 Boiling Point 232.6±0.0 °C at 760 mmHg
Molecular Formula C9H20O4Si2 Melting Point N/A
MSDS Chinese USA Flash Point 65.3±15.4 °C
Symbol GHS02
GHS02
Signal Word Warning

 Names

Name bis(trimethylsilyl) propanedioate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 232.6±0.0 °C at 760 mmHg
Molecular Formula C9H20O4Si2
Molecular Weight 248.424
Flash Point 65.3±15.4 °C
Exact Mass 248.090012
PSA 52.60000
LogP 2.39
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.420
Storage condition 2-8°C

 Safety Information

Symbol GHS02
GHS02
Signal Word Warning
Hazard Statements H226
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F: Flammable;
Risk Phrases R11
Safety Phrases S16
RIDADR UN 3272 3/PG 2
WGK Germany 3
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~83%

Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Stadlbauer, Wolfgang; Badawey, El-Sayed; Hojas, Gerhard; Roschger, Peter; Kappe, Thomas Molecules, 2001 , vol. 6, # 4 p. 338 - 352

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: US4584133 A1, ;

~94%

Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Palomo, C. Synthesis, 1981 , # 10 p. 809 - 811

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Tetrahedron Letters, , vol. 30, # 23 p. 3073 - 3076

~89%

Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Jueschke, Ralf; Sartori, Peter Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1996 , vol. 51, # 12 p. 1691 - 1700

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Detail
Literature: Environmental Science and Technology, , vol. 32, # 16 p. 2357 - 2370

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Central European Journal of Chemistry, , vol. 9, # 5 p. 813 - 824

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Chemische Berichte, , vol. 109, p. 1701 - 1707

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Bis(trimethylsilyl) malonate Structure

Bis(trimethylsi...

CAS#:18457-04-0

Literature: Canadian Journal of Chemistry, , vol. 50, p. 3913 - 3916

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles4

More Articles
Monomeric malonate precursors for the MOCVD of HfO2 and ZrO2 thin films.

Dalton Trans. (4) , 654-63, (2009)

New Hf and Zr malonate complexes have been synthesized by the reaction of metal amides with different malonate ligands (L = dimethyl malonate (Hdmml), diethyl malonate (Hdeml), di-tert-butyl malonate ...

Synth. Commun. 15 , 1039, (1985)

Synthesis of ß-Keto Acids and Methyl Ketones Using Bis (trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides. Rathke MW and Nowak MA.

Synth. Commun. 15(12) , 1039-49, (1985)

 Synonyms

Propanedioic acid, bis(trimethylsilyl) ester
malonic acid bis-trimethylsilanyl ester
dimethyl malonate
Bis(trimethylsilyl) malonate
EINECS 242-342-5
MALONIC ACID, BIS(TRIMETHYLSILYL) ESTER
MFCD00009631
Malonic Acid Bis(trimethylsilyl) Ester