(2-Iodophenyl)acetonitrile
(2-Iodophenyl)acetonitrile structure
|
Common Name | (2-Iodophenyl)acetonitrile | ||
|---|---|---|---|---|
| CAS Number | 40400-15-5 | Molecular Weight | 243.044 | |
| Density | 1.8±0.1 g/cm3 | Boiling Point | 306.0±17.0 °C at 760 mmHg | |
| Molecular Formula | C8H6IN | Melting Point | 24 - 30 °C | |
| MSDS | Chinese USA | Flash Point | 138.8±20.9 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
|
Palladium(II)-Catalyzed Annulation of Alkynes with 2-(Cyanomethyl)phenylboronates Leading to 3,4-Disubstituted 2-Naphthalenamines.
J. Org. Chem. 81(5) , 1733-45, (2016) 1,2-Bis(diphenylphosphino)ethane (dppe)-ligated palladium(II) complexes catalyze the annulation of internal alkynes with 2-(cyanomethyl)phenylboronates to provide 3,4-disubstituted-2-naphthalenamines in good yields. The annulation reaction proceeds under mild... |
|
|
4,6-O-[1-cyano-2-(2-iodophenyl)ethylidene] acetals. improved second-generation acetals for the stereoselective formation of beta-D-mannopyranosides and regioselective reductive radical fragmentation to beta-D-rhamnopyranosides. scope and limitations.
J. Org. Chem. 71(9) , 3452-63, (2006) The [1-cyano-2-(2-iodophenyl)]ethylidene group is introduced as an acetal-protecting group for carbohydrate thioglycoside donors. The group is easily introduced under mild conditions, over short reaction times, and in the presence of a wide variety of other p... |
|
|
Palladium-catalyzed carboxamidation reaction and aldol condensation reaction cascade: A facile approach to ring-fused isoquinolinones. Chouhan G and Alper H.
Org. Lett. 10(21) , 4987-4990, (2008)
|
|
|
Palladium-catalyzed borylation of ortho-substituted phenyl halides and application to the one-pot synthesis of 2,2'-disubstituted biphenyls. Baudoin O, et al.
J. Org. Chem. 65(26) , 9268-9271, (2000)
|
|
|
Studies in Acyl C− H Activation via Aryl and Alkyl to Acyl “Through Space” Migration of Palladium. Kesharwani T, et al.
Org. Lett. 11(12) , 2591-2593, (2009)
|