trans-Cinnamonitrile
trans-Cinnamonitrile structure
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Common Name | trans-Cinnamonitrile | ||
|---|---|---|---|---|
| CAS Number | 1885-38-7 | Molecular Weight | 129.159 | |
| Density | 1.0±0.1 g/cm3 | Boiling Point | 263.8±0.0 °C at 760 mmHg | |
| Molecular Formula | C9H7N | Melting Point | 18-20 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 105.2±11.2 °C | |
| Symbol |
GHS07 |
Signal Word | Warning | |
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The spectroscopy and photochemistry of quinioline structural isomers: (E)- and (Z)-phenylvinylnitrile.
J. Chem. Phys. 143 , 074304, (2015) In Titan's atmosphere, photochemical pathways that lead to nitrogen heteroaromatics may incorporate photoisomerization of their structural isomers as a final step. (E)- and (Z)-phenylvinylnitrile ((E)- and (Z)-PVN, C6H5-CH=CHCN) are structural isomers of quin... |
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Reversible targeting of noncatalytic cysteines with chemically tuned electrophiles.
Nat. Chem. Biol. 8 , 471-6, (2012) Targeting noncatalytic cysteine residues with irreversible acrylamide-based inhibitors is a powerful approach for enhancing pharmacological potency and selectivity. Nevertheless, concerns about off-target modification motivate the development of reversible cy... |
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Formation of mercapturic acids from acrylonitrile, crotononitrile, and cinnamonitrile by direct conjugation and via an intermediate oxidation process.
Drug Metab. Dispos. 9(3) , 246-9, (1981) After administration of acrylonitrile, crotononitrile and cinnamonitrile to rats, two types of mercapturic acids were isolated from urine and identified by mass and NMR spectroscopy as N-acetyl-S-(2-cyanoethyl)-L-cysteine (I) and N-acetyl-S-(2-hydroxyethyl)-L... |
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Synthesis and use of an in-solution ratiometric fluorescent viscosity sensor.
Nat. Protoc. 2(1) , 227-36, (2007) A procedure for the synthesis of a ratiometric viscosity fluorescent sensor is described in this protocol. The essential requirement for the design of this sensor is the attachment of a primary fluorophore that has both a viscosity-independent fluorescence em... |
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Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
Org. Biomol. Chem. 8(18) , 4071-3, (2010) A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant. |
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Use of achiral/chiral SFC/MS for the profiling of isomeric cinnamonitrile/hydrocinnamonitrile products in chiral drug synthesis.
Anal. Chem. 78(11) , 3835-8, (2006) A directly coupled achiral/chiral SFC/MS method has been developed for the profiling of a three-step stereoselective synthesis of cinnamonitrile and hydrocinnamonitrile intermediates. Semipurified reaction mixtures were screened in one step to determine the d... |
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Fluorogenic surrogate substrates for toluene-degrading bacteria--are they useful for activity analysis?
J. Microbiol. Methods 70(2) , 272-83, (2007) Cultivated bacterial toluene degraders use one or several of four described pathways for the aerobic degradation of this priority groundwater contaminant. To be able to identify un-cultivated toluene-degrading bacteria within enriched or natural consortia, we... |