Cyclopropylboronic acid
Cyclopropylboronic acid structure
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Common Name | Cyclopropylboronic acid | ||
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| CAS Number | 411235-57-9 | Molecular Weight | 85.90 | |
| Density | 1.1±0.1 g/cm3 | Boiling Point | 205.1±23.0 °C at 760 mmHg | |
| Molecular Formula | C3H7BO2 | Melting Point | 90-95 °C(lit.) | |
| MSDS | Chinese USA | Flash Point | 77.9±22.6 °C | |
| Symbol |
GHS05, GHS07, GHS08 |
Signal Word | Danger | |
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Palladium-catalyzed decarboxylative coupling of isatoic anhydrides with arylboronic acids.
Org. Lett. 13 , 6114-6117, (2011) The decarboxylative coupling of isatoic anhydrides with arylboronic acids was realized for the first time in the presence of Pd(2)(dba)(3) and DPEphos, achieving aryl o-aminobenzoates with yields ranging from moderate to good. The efficiency of this procedure... |
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Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways.
J. Am. Chem. Soc. 128 , 12634, (2006) Palladium-catalyzed alkylations of sp2 and sp3 C-H bonds with either methylboroxine or alkylboronic acids were developed. Ag2O or AgCO3 is used as a crucial oxidant and promoter for the transmetalation step. Ether, ester, alcohol, and alkene functional groups... |
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Copper-mediated N-cyclopropylation of azoles, amides, and sulfonamides by cyclopropylboronic acid.
J. Org. Chem. 73 , 6441, (2008) Reaction of azoles, amides, and sulfonamides in dichloroethane with readily available cyclopropylboronic acid in the presence of copper acetate and sodium carbonate afforded the N-cyclopropyl derivatives in good to excellent yields. |
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2-(2-Aminothiazol-4-yl)pyrrolidine-based tartrate diamides as potent, selective and orally bioavailable TACE inhibitors.
Bioorg. Med. Chem. Lett. 10th ed., 21 , 3172-3176, (2011) TNF-α converting enzyme (TACE) inhibitors are promising agents to treat inflammatory disorders and cancer. We have investigated novel tartrate diamide TACE inhibitors where the tartrate core binds to zinc in a unique tridentate fashion. Incorporating (R)-2-(2... |
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Tetrahedron Lett. 43 , 6987-6990, (2002)
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Microwave-assisted N-cyclopropylation of pyridinols with cyclopropyl boronic acid Tambe, Y. B.; et al.
Synth. Commun. 9th ed., 42 , 1341-1348, (2012)
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Ni- and Cu-catalyzed coupling reactions using 2-(4,5-dihydro-1H-imidazo-2-yl)phenol as a versatile phosphine-free ligand Haneda, S.; Sudo, K.; Hayashi, M.
Heterocycles 1st ed., 84 , 569-575, (2012)
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Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle Zhang, M.; et al.
Tetrahedron 3rd ed., 68 , 900-905, (2012)
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Palladium(0)-catalyzed cyclopropane C-H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives Rousseaux, S.; Liegault, B.; Fagnou, K.
Chem. Sci. 1st ed., 3 , 244-248, (2012)
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Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes Kubota, A.; Sanford, M. S.
Synthesis 16 , 2579-2589, (2011)
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