vanadium oxytrifluoride

vanadium oxytrifluoride Structure
vanadium oxytrifluoride structure
Common Name vanadium oxytrifluoride
CAS Number 13709-31-4 Molecular Weight 123.93600
Density 2.45 Boiling Point 480 °C
Molecular Formula F3OV Melting Point 300 °C
MSDS Chinese USA Flash Point N/A
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

The gas-phase on-line production of vanadium oxytrihalides, VOX3 and their identification by infrared spectroscopy.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56(14) , 2693-8, (2000)

A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the following heated salts NaF, KBr and KI at 375, 700 and 550 degrees ...

Synthesis of tylocrebrine and related phenanthroindolizidines by VOF3-mediated oxidative aryl-alkene coupling.

Org. Lett. 13(2) , 196-9, (2011)

A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in the final step, which enables regioselective preparation of ...