vanadium oxytrifluoride

Modify Date: 2024-01-02 15:28:19

vanadium oxytrifluoride Structure
vanadium oxytrifluoride structure
Common Name vanadium oxytrifluoride
CAS Number 13709-31-4 Molecular Weight 123.93600
Density 2.45 Boiling Point 480 °C
Molecular Formula F3OV Melting Point 300 °C
MSDS Chinese USA Flash Point N/A
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name Vanadium(V) Trifluoride Oxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.45
Boiling Point 480 °C
Melting Point 300 °C
Molecular Formula F3OV
Molecular Weight 123.93600
Exact Mass 123.93400
PSA 17.07000
LogP 1.14180

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302 + H312 + H332-H314
Supplemental HS Contact with acids liberates very toxic gas.
Precautionary Statements P280-P305 + P351 + P338-P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C,Xi
Risk Phrases R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R32:Contact with acids liberates very toxic gas. R34:Causes burns.
Safety Phrases S26-S36/37/39-S45
RIDADR UN 3260 8/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 6.1

 Synthetic Route

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vanadium oxytrifluoride Structure

vanadium oxytri...

CAS#:13709-31-4

Literature: V: MVol.B1, 90, page 243 - 246 Dehnicke, K. (Angew. Chem. 77 (1965) 22/9)

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vanadium oxytrifluoride Structure

vanadium oxytri...

CAS#:13709-31-4

Literature: Journal of the Chemical Society, , p. 2979 - 2982 V: MVol.B1, 90, page 243 - 246

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vanadium oxytrifluoride Structure

vanadium oxytri...

CAS#:13709-31-4

Literature: S: SVol.3, 3.1.7.6.3.1, page 306 - 307

 Articles2

More Articles
The gas-phase on-line production of vanadium oxytrihalides, VOX3 and their identification by infrared spectroscopy.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 56(14) , 2693-8, (2000)

A new route has been devised, leading to the production of VOX3 molecules where X=F, Br and I by an on-line process using vanadium oxytrichloride, VOCl3 as a starting compound passed over the followin...

Synthesis of tylocrebrine and related phenanthroindolizidines by VOF3-mediated oxidative aryl-alkene coupling.

Org. Lett. 13(2) , 196-9, (2011)

A highly convergent strategy to prepare phenanthroindolizidines is reported involving three consecutive C-C coupling reactions. This sequence features a novel VOF(3)-mediated aryl-alkene coupling in t...

 Synonyms

VANADIUM OXYTRIFLUORIDE
EINECS 237-250-7
Vanadium(V) trifluoride oxide
MFCD00042555